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Title :Biosynthesis of violacein: a genuine intermediate, protoviolaceinic acid, produced by VioABDE, and insight into VioC function
Authors :Shinoda, Kouhei
Hasegawa, Takuji
Sato, Hiroaki
Shinozaki, Masaaki
Kuramoto, Hirotomo
Takamiya, Yosuke
Sato, Tsutomu
Nikaidou, Naoki
Watanabe, Takeshi
Hoshino, Tsutomu
Publisher :Royal Society of Chemistry
Issue Date :2007
Journal Title :Chemical communications
Volume :2007
Issue :40
Start Page :4140
End Page :4142
ISSN :1359-7345
Abstract :A biosynthetic intermediate of violacein produced by the mixed enzymes of VioABDE was elucidated to be 5-(5-hydroxy-1H-indol-3-yl)-3-(1H-indol-3-yl)-1H-pyrrole-2-carboxylic acid, named protoviolaceinic acid, indicating that VioC, responsible for the final biosynthetic step, works to oxygenate at the 2-position of the right side indole ring, and that the oxygenation reaction to form the central pyrrolidone core proceeds in a non-enzymatic fashion.
Type Local :学術雑誌論文
Language :eng
Format :application/pdf
URI :http://hdl.handle.net/10191/25032
fullTextURL :http://dspace.lib.niigata-u.ac.jp/dspace/bitstream/10191/25032/1/2007_4140-4142.pdf
DOI :info:doi/10.1039/B705358D
Appears in Collections:10 査読済論文 = Postprint

Please use this identifier to cite or link to this item: http://hdl.handle.net/10191/25032